Heterometallic cuboidal complexes as derivatives of the [MO3S4(H2O)9]4+cluster
β Scribed by David M. Saysell; A. Geoffrey Sykes
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 752 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1040-7278
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Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from (Mo3S4(H2O)9)4+: X-Ray Structure of the Single Cube with an Mo3SnS4 Core. -The solution chemistry of the single and double cuboidal clusters ( Mo3SnS4(H2O)12)6+ and (Mo6SnS8(H2O)18)8+ is studied and the struc
The reaction of trinuclear MO(N), incomplete cuboidal complexes [Mo,S,(H,O),]~+, [Mo,OS,(H,O),]~+ and Fro,W,W,W4+ with BH.,-in aqueous HCl solutions results in the conversion of core ligands A-S to h-0. In combination with Dowex cation-exchange chromatography the procedure can be used on a preparati
4 (NCS) 9 ] β’0.5H 2 O (space group C2/c, monoclinic, Z = 8) and for [Mo 6 SnSe 8 (H 2 O) 18 ] (TosO -) 8 β’2TosOHβ’28H 2 O (space group P1, triclinic, Z = 1). The latter one is the first example of an Se-containing corner-shared double cube. Conversion of single cubes into corner-shared double cubes i