Heterocyclic Studies. XV. 5-Methyl-4-phenylpyrazole-1-acetic Acid. An Oxidation Product of 2,3-Dihydro-5-methyl-6-phenyl-4H-1,2-diazepin-4-one *,1
β Scribed by Moore, James A.; Habraken, Clarisse L.
- Book ID
- 126917514
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 553 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
In the molecule of the title compound, C 9 H 9 N 3 O, the dihedral angle between the planar rings is 7.49 (3) . In the crystal structure, intermolecular N-HΓ Γ ΓO hydrogen bonds link the molecules into dimers, which may be effective in the stabilization of the crystal structure.
All interatomic distances in the title compound, C~13~H~15~N~3~O~2~S, are normal. The 1,2,4-triazole ring is planar and is inclined at 46.50β (6)Β° to the phenyl ring. The ethoxycarbonylmethyl group is also close to being planar and is inclined at 87.54β (9)Β° to the 1,2,4-triazole ring. The crystal was
All interatomic distances in the title compound, C~5~H~7~N~3~O~2~S, are normal. The 1,2,4-triazoline ring is planar and it is inclined at 78.61β (7)Β° to the planar acetic acid group. The molecules of the title compound are connected __via__ OβH...N hydrogen bonds into zigzag chains along the [101] di