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Hetero-Bimetallic Ni-Rh Carbido Carbonyl Clusters: Synthesis, Structure and 13C NMR of [Ni10Rh2C(CO)20]2–, [Ni9Rh3C(CO)20]3– and [Ni6Rh8(C2)2(CO)24]4–

✍ Scribed by Cristina Femoni; Maria Carmela Iapalucci; Giuliano Longoni; Stefano Zacchini


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
608 KB
Volume
2009
Category
Article
ISSN
1434-1948

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✍ Roberto Della Pergola; Annalisa Sironi; Carlo Manassero; Mario Manassero 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB 👁 1 views

## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip