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Helix — coil transition of poly-(ε-carbobenzyloxy-l-lysine) in m-cresol

✍ Scribed by Toshio Hayashi; Shingo Emi; Akio Nakajima

Book ID
103350802
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
448 KB
Volume
16
Category
Article
ISSN
0032-3861

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## Abstract Helix–coil transitions of poly(ε‐carbobenzyloxy L‐lysine) (PCBL) in __m__‐cresol and in mixtures of dichloroacetic acid (DCA) and ethylene dichloride (EDC) were investigated by optical rotation measurements, with special interest in the molecular‐weight dependence of helical content. Th

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In this paper two points are considered: the methods of evaluating the helical content 8 and the calculation of the parameters of the transition from experimental data and its interpretation. The parameter AH obtained is in good agreement with the calorimetric one and v is found to be independent of