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Helix-Coil Transition of Poly(N ε -carbobenzoxy-L-lysine) in Solutions Containing Trifluoroacetic Acid

✍ Scribed by Štokrová, Š.; Fišer, V.; Bláha, K.


Book ID
127373198
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
354 KB
Volume
6
Category
Article
ISSN
0024-9297

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Helix–coil transition in poly(γ-benzyl-L
✍ M. Cortijo; A. Roig; F. Garcia Blanco 📂 Article 📅 1969 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 440 KB 👁 1 views

In this paper two points are considered: the methods of evaluating the helical content 8 and the calculation of the parameters of the transition from experimental data and its interpretation. The parameter AH obtained is in good agreement with the calorimetric one and v is found to be independent of

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✍ A. Roig; F. García Blanco; M. Cortijo 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 353 KB 👁 1 views

## Abstract The thermal helix–coil transition of poly(γ‐benzyl L‐glutamate‐__co__‐ε‐carbobenzoxy‐L‐lysine) copolypeptides was studied in solvent mixtures of different compositions. The cooperativity parameter __v__ changes linearly with polymer (and solvent) composition, whereas the heat of the tra

Enthalpy of helix–coil transitions from
✍ Giovanni Giacometti; Angklo Turolla; Renzo Boni 📂 Article 📅 1970 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 352 KB 👁 1 views

## Abstract The heal of solution of Poly‐ε‐carbobenzoxy‐L‐lysine and of a series of its copolymers with phenylalanine was measured as a function of solvent composition. The enthalpy change of the helix‐to‐coil transition was estimated for the various cases. The previous findings that side chains do