Dielectric Dispersion of Polypeptide Solutions. II. Helix-Coil Transition of Poly(iε-carbobenzoxy-L-lysine) in m-Cresol
✍ Scribed by Omura, Ikuo; Teramoto, Akio; Fujita, Hiroshi
- Book ID
- 127377058
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 750 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The heal of solution of Poly‐ε‐carbobenzoxy‐L‐lysine and of a series of its copolymers with phenylalanine was measured as a function of solvent composition. The enthalpy change of the helix‐to‐coil transition was estimated for the various cases. The previous findings that side chains do
## Abstract The thermal helix–coil transition of poly(γ‐benzyl L‐glutamate‐__co__‐ε‐carbobenzoxy‐L‐lysine) copolypeptides was studied in solvent mixtures of different compositions. The cooperativity parameter __v__ changes linearly with polymer (and solvent) composition, whereas the heat of the tra
## Abstract Helix–coil transitions of poly(ε‐carbobenzyloxy L‐lysine) (PCBL) in __m__‐cresol and in mixtures of dichloroacetic acid (DCA) and ethylene dichloride (EDC) were investigated by optical rotation measurements, with special interest in the molecular‐weight dependence of helical content. Th
The helix-coil transitions for poly-L-lysine (PL) were investigated by the methods of spectropolarimetry, viscometry and potentiometric titration in 0.2M NaCl a t different temperatures as well as in 0.2M NaBr, 1M KC1, and in mixtures of 0.2M NaCl or NaBr with methanol a t room temperature. The enth