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Gold Catalysis: Alkyl Migration in the Addition of Alcohols to Nitriles

✍ Scribed by Nada Ibrahim; A. Stephen K. Hashmi; Frank Rominger

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
270 KB
Volume
353
Category
Article
ISSN
1615-4150

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πŸ“œ SIMILAR VOLUMES

Polar Effects in the Addition of Alkyl R
Polar Effects in the Addition of Alkyl Radicals to Olefins
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. JΓΌrgen Meister πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 2 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image