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Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes

✍ Scribed by J. Henrique Teles; Stefan Brode; Mathieu Chabanas

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 110 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980605)37:10<1415::aid-anie1415>3.0.co;2-n

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**Lauding the rings** in the realm of metal‐catalyzed cyclizations, where many mechanistic shadows lie: Gold is master, particularly in reactions that proceed through metal cyclopropylcarbene intermediates. In their Communication on page 2402 ff., A. M. Echavarren and co‐workers report on their ques