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Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for the exo- and endo-Cyclization of Enynes

✍ Scribed by Cristina Nieto-Oberhuber; M. Paz Muñoz; Elena Buñuel; Cristina Nevado; Diego J. Cárdenas; Antonio M. Echavarren

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
183 KB
Volume
116
Category
Article
ISSN
0044-8249

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**Lauding the rings** in the realm of metal‐catalyzed cyclizations, where many mechanistic shadows lie: Gold is master, particularly in reactions that proceed through metal cyclopropylcarbene intermediates. In their Communication on page 2402 ff., A. M. Echavarren and co‐workers report on their ques

ChemInform Abstract: Cationic Gold(I) Co
ChemInform Abstract: Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes.
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1998 catalysis, phase-transfer catalysis catalysis, phase-transfer catalysis O 0020 35 -040 Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes. -Cationic gold(I) complexes, generated in situ by reaction of [ligand-AuMe] with Lewis or Broensted acids, are e