ChemInform Abstract: Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes.

✍ Scribed by J. H. TELES; S. BRODE; M. CHABANAS

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199835040

✦ Synopsis

1998 catalysis, phase-transfer catalysis catalysis, phase-transfer catalysis O 0020 35 -040 Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes. -Cationic gold(I) complexes, generated in situ by reaction of [ligand-AuMe] with Lewis or Broensted acids, are effective catalysts for the addition of alcohols to alkynes as demonstrated by synthesis of compound (III) (11 further examples presented without definite reaction conditions and yields). -(TELES,