## Abstract Relatively stable equimolar adducts of 1,3,5‐trinitro‐1,3,5‐triazacyclohexane were prepared with 2,6‐lutidine‐N‐oxide, 4‐hydroxy‐1‐butanesulfonic acid δ‐sultone (1,4‐butane sultone), and 2,2,6,6‐tetramethyl‐4‐piperidone‐1‐oxyl. Only the last adduct is selective for RDX; the others also
Geometric structure of molecule of 1,3,5-trinitro-1,3,5-triazacyclohexane in the gas phase
✍ Scribed by I. F. Shishkov; T. L. El'fimova; L. V. Vilkov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1992
- Tongue
- English
- Weight
- 349 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-4766
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📜 SIMILAR VOLUMES
The kinetics of the thermal decomposition of RDX and the formation of three nitroso intermediates have been studied in hexaproteo (h6) benzene; hexadeutero (d6) benzene at 180"C and 200"C; and, as a melt at 210°C in sealed capillaries. Decomposition rates were determined by vapor-phase chromatograph
## Abstract Procedures are described for the synthesis of 1,3,5‐trinitro‐1,3,5‐triazacyclohexane (RDX), 1,3,5,7‐tetranitro‐1,3,5,7‐tetraazacyclooctane (HMX) fully labeled with nitrogen‐15.
RDX is one of the most important military explosives. It is a component of some plastic explosives which are frequently used in terrrorist attacks. Two fluorimetric methods have been described for the quantitative determination of RDX which are based on the detection of nitrite ions. After a basic