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New adducts of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX)

✍ Scribed by W. Selig

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
447 KB
Volume
6
Category
Article
ISSN
0721-3115

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✦ Synopsis

Abstract

Relatively stable equimolar adducts of 1,3,5‐trinitro‐1,3,5‐triazacyclohexane were prepared with 2,6‐lutidine‐N‐oxide, 4‐hydroxy‐1‐butanesulfonic acid δ‐sultone (1,4‐butane sultone), and 2,2,6,6‐tetramethyl‐4‐piperidone‐1‐oxyl. Only the last adduct is selective for RDX; the others also form adducts with 1,3,5,7‐tetranitro‐1,3,5,7‐tetrazacyclooctane. A very labile RDX adduct is formed with tetrahydrothiophene‐1‐oxide. Some properties of the new adducts are presented.

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