Generation of Nitrile Oxides from Oximes Using t-BuOI and Their Cycloaddition
β Scribed by Minakata, Satoshi; Okumura, Sota; Nagamachi, Toshiki; Takeda, Youhei
- Book ID
- 111691651
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 974 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1523-7060
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchl
Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions. -Aldoximes and ketoximes (II) are readily synthesized from aldehydes and ketones (I) on Al 2 O 3 under microwave irradiation.