𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of oximes, conversion to nitrile oxides and their subsequent 1,3-dipolar cycloaddition reactions under microwave irradiation and solvent-free reaction conditions

✍ Scribed by Béatrice Touaux; Françoise Texier-Boullet; Jack Hamelin

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
147 KB
Volume
9
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchlorosuccinimide and alkenes or alkynes over alumina under microwave irradiation to give isoxazolines or isoxazoles.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of Oximes
ChemInform Abstract: Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions.
✍ B. TOUAUX; F. TEXIER-BOULLET; J. HAMELIN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions. -Aldoximes and ketoximes (II) are readily synthesized from aldehydes and ketones (I) on Al 2 O 3 under microwave irradiation.

ChemInform Abstract: 1,3-Dipolar Cycload
ChemInform Abstract: 1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides in the Synthesis of Natural Compounds and Their Analogues
✍ A. I. Kotyatkina; V. N. Zhabinsky; V. A. Khripach 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 3 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Improvement and Simplification of Synthe
Improvement and Simplification of Synthesis of 3-Aryloxy-1,2-epoxypropanes Using Solvent-Free Conditions and Microwave Irradiations. Relation with Medium Effects and Reaction Mechanism.
✍ Beata K. Pchelka; Andre Loupy; Alain Petit 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 21 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.