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Oxidative Regeneration of Carbonyl Compounds from Their Oximes Using in situ Generated Superoxide.

✍ Scribed by K. N. Singh; Jyotsna Pandey; Manorama Singh


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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Kinetics and mechanism of the oxidative
✍ Pradeep K. Sharma πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 80 KB

## Abstract The oxidative deoximination of several aldo‐ and keto‐oximes by pyridinium bromochromate (PBC), in dimethylsulfoxide, exhibited a first‐order dependence on both the reductant (oxime) and the oxidant (PBC). The oxidation of ketoximes is slower than that of aldoximes. The rates of oxidati