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ChemInform Abstract: Generation of Nitrile Oxides from Oximes Using t-BuOI and Their Cycloaddition.
β Scribed by Satoshi Minakata; Sota Okumura; Toshiki Nagamachi; Youhei Takeda
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 46 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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Cycloaddition of Nitrile Oxides to (60)Fullerene. -Addition of nitrile oxides to (60)fullerene gives fullerene-fused isoxazolines (cf. (III)), which can regenerate the (60)fullerene under relatively mild conditions. -(DA
Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions. -Aldoximes and ketoximes (II) are readily synthesized from aldehydes and ketones (I) on Al 2 O 3 under microwave irradiation.