Generation and reactions of 3-lithio-1-(phenylsulfonyl)indole
✍ Scribed by Saulnier, Mark G.; Gribble, Gordon W.
- Book ID
- 111964315
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 677 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
In the title molecule, C 21 H 17 NO 3 S 2 , the sulfonyl-bound and sulfinyl-bound phenyl rings form dihedral angles of 82.04 (5) and 26.26 (8) , respectively, with the indole ring system. In the crystal structure C-HÁ Á ÁO, C-HÁ Á Á andinteractions form a two-dimensional network.
The crystal structure of the title compound, C 14 H 10 N 2 O 4 S, confirms the position of the nitro group at position C-3 of the indole ring system. While the nitro group is coplanar with the indole ring system, the angle between the indole and phenyl planes is 83.9 (3) .
The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.