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General approach to highly functionalized benzylic organometallics of zinc and copper

โœ Scribed by Berk, Scott C.; Knochel, Paul; Yeh, Ming Chang P.


Book ID
111923116
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
336 KB
Volume
53
Category
Article
ISSN
0022-3263

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Preparation of functionalized zinc and c
โœ Sidduri AchyuthaRao; Charles E. Tucker; Paul Knochel ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 282 KB

a-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 Oc (05-2 h), affording surfur stabilized organozinc derivatives of type 2. The presence of a functional group such as an ester or a cyan0 group is tolerated in these organometallics. After a transmelallation to the corresponding copper