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A general preparation of highly functionalized zinc and copper organometallics at the .alpha.-position to an oxygen

โœ Scribed by Chou, Tso Sheng; Knochel, Paul


Book ID
126140282
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
253 KB
Volume
55
Category
Article
ISSN
0022-3263

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Preparation of functionalized zinc and c
โœ Sidduri AchyuthaRao; Charles E. Tucker; Paul Knochel ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 282 KB

a-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 Oc (05-2 h), affording surfur stabilized organozinc derivatives of type 2. The presence of a functional group such as an ester or a cyan0 group is tolerated in these organometallics. After a transmelallation to the corresponding copper