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Preparation of highly functionalized magnesium, zinc, and copper aryl and alkenyl organometallics via the corresponding organolithiums

✍ Scribed by Tucker, Charles E.; Majid, Tahir N.; Knochel, Paul


Book ID
111686751
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
969 KB
Volume
114
Category
Article
ISSN
0002-7863

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Preparation of functionalized zinc and c
✍ Sidduri AchyuthaRao; Charles E. Tucker; Paul Knochel πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 282 KB

a-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 Oc (05-2 h), affording surfur stabilized organozinc derivatives of type 2. The presence of a functional group such as an ester or a cyan0 group is tolerated in these organometallics. After a transmelallation to the corresponding copper