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Gas phase reactions of SiF2 with F2 and Cl2

✍ Scribed by A.C. Stanton; A. Freedman; J. Wormhoudt; P.P. Gaspar

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 437 KB
Volume: 122
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80561-3

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✦ Synopsis

Reaclrons of

SlF2 rndlcnls have been sludled m a fast-flow syslem Rate conskm~s at 295 K of (47&03)~10-'~ cm' molecule-' s-' for the reactIon of SIFT + F2. and (5 1 +_O 6)X1O-'3 cm' molecule-' s -' for SIF, + Cl, were obtamed No reacuon was observed with O2 and Hz SIF, wz detected by laser-Induced fluorescence and hfellme observations and an excllntlon speclrum are reporled Volume 122, number 3 CHEMICAL PHYSICS LETTERS

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