## The reaction (3) i-CpF, + CCli-C3F&l + CCl3 was investigated in the gas phase over the range 80-225°C using the photolysis of heptafluoroisopropyl iodide as the source of radicals. The rate constant, based on the value of 1013 36 cm3 mol log(k3/cm3 mol-' s-l) = (13.10 2 0.20) -(14000 \* 280)/0
Gas-phase photodecomposition of carbon tetrachloride
✍ Scribed by R.E. Rebbert; P.J. Ausloos
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 869 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0047-2670
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📜 SIMILAR VOLUMES
The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 x 1013 cm3 mol-' s-' for the self-combination rate constant of all
## Abstract The rate constant for the combination of trichloromethyl radicals in the gas phase has been measured by applying the rotating sector technique to the gas phase carbon tetrachloride–cyclohexane photochemical system. A temperature‐independent rate constant, __k__~5~, of 3.9 ± 1.0 × 10^12^