Gas-phase combination reactions of SF4and SF5with F in plasmas of SF6
โ Scribed by K. R. Ryan; I. C. Plumb
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 567 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0272-4324
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๐ SIMILAR VOLUMES
The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/
The gas phase chemical kinetics of SF,, SF5, and SLF,, are reviewed with particular emphasis on relevance to the general problem of the dielectric breakdown of SFs. Specific reaction systems treated are SF, + F,, SF, + SF,, and the pyrolysis of S2Flo. Computer modeling calculations were carried out
I b~srr(~ f~?iir E\p2nrrrenrolpll~srh, Unrrersmi~ Hamburg, \_ WOO Hamburg 36. Federal Reprrblrc of German) Recerred II August 1980 The chemllummescence speclra of the reactions of LI, Na, and K with SF6 and SFJ are recorded Beslde mtense afomlc spscira of the alkah aroms and a quasi-contmuum \_, a w