The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/
Drift-tube studies of SF3+ and SF5+ ions in SF6 gas
β Scribed by Z.A. Talib; M. Saporoschenko
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 714 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0168-1176
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π SIMILAR VOLUMES
The gas-phase stabilities of cluster ions SF m (+) (SF6) n with m = 0-5 were determined by using a high pressure mass spectrometer. The bond energies of SF m (+) (SF6)1 were found to be less than 10 kcal/mol and to decrease with m = 0 β 5. There appear to be rather large gaps in the bond energies be
The dwowuon of STsCI and CFS1 scnslttzed by multIphoton cwtation of SF6 by a pulsed CO1 Iascr has been studxd vrrsus prcssurc. laser lluence, mert gasend oplical frcqucncy. lsoto P \_ IC cfrccls have been obscrvcd bclwccn 3zST~Cl/37S~~CI and bcrwccn '3Cr#\*Cr31 and selccriv~ty factors as tngh as (r&