Galvanostatic study of the electrochemical reduction of organomercury salts
β Scribed by A.B. Ershler; V.V. Strelets; K.P. Butin; A.N. Kashin
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 684 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-0728
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β¦ Synopsis
In ref. l0 the value of the order of 5 s was obtained * This proves once more that the reaction (4) should be excluded from the list of possible reaction steps m the case of 2-naphthylmercury acetate. * At high concentrations the polarogram of this compound shows two waves and the charging curve two plateaus one of the electrolysis products blocks the surface
π SIMILAR VOLUMES
The polarographic behavior of organomercury compounds has been studied by various workers 1 -5. Most of these investigators limit themselves to the study of homologous aliphatic mercury halides, acetates and sulphates. Some reports have also appeared for the reduction of aromatic-mercury halides and
Abstracf-The anodic and cathodic polarization curves of bromine-active carbon electrode in the fused eutectic AgBr + KBr at 400-700Β°C have been determined by the galvanostatic method. The amount of adsorbed halogen has been calculated as a function of potential and interpreted on the basis of Langmu
Abstrati-The electrodeposition of silicon from SiO, dissolved in molten cryolite has been investigated using chronopotentiometry at nickel working electrodes. The reduction mechanism involves the slow predissociation of a silica complex to form an electroactive species: where the equilibrium constan
## Galvanostatic Apjt curves recorded at instantaneous changes in current density are examined in the case of the irreversible electrode process, whose rate is determined by the slow discharge step. Corresponding equations, taking into account the current consumption for double layer charging, the