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Further evidence for single electron transfer during the alkylation of the benzophenone anil dianion

โœ Scribed by Smith, James G.; Irwin, Douglas C.


Book ID
126914069
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
402 KB
Volume
102
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Evidence for a single electron transfer
โœ E.C. Ashby; J.N. Argyropoulos ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 273 KB

The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.

Evidence for single electron transfer in
โœ E.C. Ashby; Dong-Hak Bae; Won-Suh Park; Robert N. Depriest; Wei-Yang Su ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.

Evidence for single electron transfer in
โœ E.C. Ashby; J.N. Argyropoulos ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

Evidence for a radical process in the reaction of the lithium enolate of propiophenone with a primary alkyl iodide was obtained by the observation of cyclization of an appropriate radical probe, by the trapping of the radical intermediate and by the comparison of the relative rates of reactions of t