Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.
โฆ LIBER โฆ
Evidence for single electron transfer in metal-halogen exchange. The reaction of organolithium compounds with alkyl halides.
โ Scribed by E.C. Ashby; Tung N. Pham; Bongjin Park
- Book ID
- 108382587
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 233 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l