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Investigation of the purity of alkali metal diphenylphosphides and their reactions with organic halides. Evidence for single electron transfer

โœ Scribed by Ashby, E. C.; Gurumurthy, R.; Ridlehuber, R. W.


Book ID
121306328
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
777 KB
Volume
58
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Evidence for a single electron transfer
โœ E.C. Ashby; R.N. DePriest; A. Tuncay; Sushil Srivastava ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l

Evidence for single electron transfer in
โœ E.C. Ashby; Dong-Hak Bae; Won-Suh Park; Robert N. Depriest; Wei-Yang Su ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.