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Spectroscopic evidence for the reduction of alkyl halides by metal hydrides via a single electron transfer mechanism

โœ Scribed by E.C. Ashby; A.B. Goel; R.N. Depriest

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
207 KB
Volume
22
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Evidence for a single electron transfer
Evidence for a single electron transfer mechanism in 1he reduction of aromatic nitrogen heterocycles with main group metal hydrides and dihydropyridyl metal complexes.
โœ E.C. Ashby; A.B. Goel ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

Direct spectroscopic (EPR) evidence is presented to support a single electron transfer mechanism to describe the reactions of various simple and complex hydrides of the main group elements and dihydropyridyl metal complexes with aromatic nitrogen heterocyclic compounds.

Evidence for a single electron transfer
Evidence for a single electron transfer mechanism in the reduction of benzophenone with lithium alkoxides
โœ E.C. Ashby; J.N. Argyropoulos ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 273 KB

The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.