Single electron transfer as a mechanistic feature in the alkylation of vicinal dianions
β Scribed by Smith, James G.; Mitchell, D. J.
- Book ID
- 120079381
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 824 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.
Evidence for a radical process in the reaction of the lithium enolate of propiophenone with a primary alkyl iodide was obtained by the observation of cyclization of an appropriate radical probe, by the trapping of the radical intermediate and by the comparison of the relative rates of reactions of t