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Free radical pathway for the baeyer-villiger reaction

✍ Scribed by J.C. Robertson; A. Swelim

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
205 KB
Volume
8
Category
Article
ISSN
0040-4039

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✦ Synopsis

There is a great deal of interest in the stereochemistry of the Baeyer-Villiger reaction and the nature of the factors which influence the preferential migration of one group over another (2,3). This communication presents evidence for a free radical pathway for this reaction in addition to the accepted cationic mechanism (4,5,6).

We have determined the migratory aptitudes of substituted phenyl in the Baeyer-Villiger reaction for a series of p,p' -unsymmetrically substituted benzophenones.

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