𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The baeyer-villiger reaction as a source of “abnormal” ozonolysis products

✍ Scribed by Paul R. Story; John R. Burgess

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
275 KB
Volume
9
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Many so-called "abnormal" ozonolysis products obtained in inert solvents have been explained in terms of rearrangement of a Criegee zwitterion intermediate. (1,2,3,4,5) We present evidence here which indicates that products of this type are, more likely, the result of subsequent Baeyer-Villiger oxidations resulting from peracid produced during the ozonolysis.

📜 SIMILAR VOLUMES

A DFT study on the mechanisms of tungste
A DFT study on the mechanisms of tungsten-catalyzed Baeyer–Villiger reaction using hydrogen peroxide as oxidant
✍ Peng Jin; Lu Zhu; Donghui Wei; Mingsheng Tang; Xiangyu Wang 📂 Article 📅 2011 🏛 Elsevier 🌐 English ⚖ 675 KB

The mechanisms of the title reaction have been studied by density functional theory (DFT) method. Two possible reaction channels, including the non-catalyzed channel (channel 1) and the catalyzed channel promoted by peroxo tungsten compound (channel 2), have been studied at the B3LYP/[LANL2DZ/6-31G(

Chemical Degradation of Lasalocid: (A) T
Chemical Degradation of Lasalocid: (A) The Mannich reaction (B) Baeyer-Villiger oxidation of the retro-aldol ketone
✍ David L. Coffen; David A. Katonak 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 509 KB

## Abstract Under __Mannich__ reaction conditions (diethylamine and formaldehyde in toluene under reflux) lasalocid (**1**) undergoes a unique transformation in which the carboxyl group is replaced by a diethylaminomethyl group. The resulting __Mannich__ base **2** was converted back to lasalocid,