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Observations on the regioselectivity of some Baeyer–Villiger reactions

✍ Scribed by Michael Harmata; Paitoon Rashatasakhon

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 121 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00616-0

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✦ Synopsis

The Baeyer-Villiger reaction of a series of compounds related to an intermediate in our synthesis of (+)-dactylol showed a pattern of regioselectivity which could be varied to a small extent as a function of substitution on the precursor. A very unusual Baeyer-Villiger reaction of a methyl ketone resulted in a product from apparent insertion of an oxygen atom into between the carbonyl carbon and the methyl group of the acetyl functionality.

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