The Baeyer-Villiger reaction of a series of compounds related to an intermediate in our synthesis of (+)-dactylol showed a pattern of regioselectivity which could be varied to a small extent as a function of substitution on the precursor. A very unusual Baeyer-Villiger reaction of a methyl ketone re
✦ LIBER ✦
Regioselective Baeyer-Villiger reaction of polyhydroxycyclohexanone derivatives
✍ Scribed by Noritaka Chida; Takahiko Tobe; Seiichiro Ogawa
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 317 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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Many so-called "abnormal" ozonolysis products obtained in inert solvents have been explained in terms of rearrangement of a Criegee zwitterion intermediate. (1,2,3,4,5) We present evidence here which indicates that products of this type are, more likely, the result of subsequent Baeyer-Villiger oxid