𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of spirocyclic bislactones substituent effects on the regioselectivity of the Baeyer-Villiger of 1,3-diketones

✍ Scribed by Janine Cossy; Barbara Gille; Véronique Bellosta

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
214 KB
Volume
39
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The Baeyer-Villiger oxidation of substituted spirocyclic lactones and 1,3-diketones led to spirocyclic bislactones with a good regioselectivity.

📜 SIMILAR VOLUMES

ChemInform Abstract: Baeyer—Villiger Oxi
ChemInform Abstract: Baeyer—Villiger Oxidation of Norbornan-7-ones: Long-Range Substituent Effects on Regioselectivity.
✍ G. MEHTA; N. MOHAL 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

Baeyer-Villiger Oxidation of Norbornan-7-ones: Long-Range Substituent Effects on Regioselectivity. -In connection with the synthesis of carba-sugars the title oxidation is investigated with different substituted norbornan-7-ones (I). In these derivatives the regioselectivity is completely controlled

Observations on the regioselectivity of
Observations on the regioselectivity of some Baeyer–Villiger reactions
✍ Michael Harmata; Paitoon Rashatasakhon 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 121 KB

The Baeyer-Villiger reaction of a series of compounds related to an intermediate in our synthesis of (+)-dactylol showed a pattern of regioselectivity which could be varied to a small extent as a function of substitution on the precursor. A very unusual Baeyer-Villiger reaction of a methyl ketone re

An unusual effect of selenium substituen
An unusual effect of selenium substituents on the regiochemistry of a baeyer-villiger rearrangement
✍ Barry M. Trost; Peter Buhlmayer; Michael Mao 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 201 KB

The regioselectivity of a Baeyer-Villiger oxidation of a cyclobutanone is dependent upon the oxidation state of a proximal selenium substituent. for the selenium dioxide-hydrogen peroxide oxidation of ketones. Sharpless, K. B. ; Gordon, K.M. J. Am. Chem. Soq . 1976, 98, 300. 9. It can be argued that