𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Evidence for a stereoelectronic effect in the baeyer-villiger reaction: Introducing the intramolecular reaction

✍ Scribed by Sosale Chandrasekhar; Chandra Deo Roy

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
128 KB
Volume
28
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

An intramolecular Baeyer-Villiger reaction has been effected involving a conformationally-fixed intermediate which breaks down with stereoelectronic control.

📜 SIMILAR VOLUMES

Free radical pathway for the baeyer-vill
Free radical pathway for the baeyer-villiger reaction
✍ J.C. Robertson; A. Swelim 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 205 KB

There is a great deal of interest in the stereochemistry of the Baeyer-Villiger reaction and the nature of the factors which influence the preferential migration of one group over another (2,3). This communication presents evidence for a free radical pathway for this reaction in addition to the acce