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Free radical additions. Part I: Free radical addition of cyclo-octane to unsaturated compounds

โœ Scribed by E. van Bruggen; H. Boelens; F. Rijkens

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
145 KB
Volume
86
Category
Article
ISSN
0165-0513

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๐Ÿ“œ SIMILAR VOLUMES

New Results of Free Radical Additions to
New Results of Free Radical Additions to Unsaturated Fatty Compounds
โœ Metzger, J. O. ;Linker, Ursula ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons โš– 435 KB

Unsaturated fatty acids such as oleic acid are 1,2-dialkyl substituted alkenes, which can be functionalized by free radical addition to the C,Cdouble bond. We have been able to add enolizable compounds, e. g. acetone, acetic acid and malonic acid to methyl oleate mediated by manga- nese(II1)acetate.

Free radical type addition of toluenesul
Free radical type addition of toluenesulfonyl cyanide to unsaturated hydrocarbons
โœ Jim-Min Fang; Ming-Yi Chen ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

By catalysis of AIBN, tosyl cyanide adds in a regio-and stereoselective manner to unsaturated hydrocarbons, including alkenes, dienes and 1-hexyne. Accompanied intramolecular cyclization and ring cleavage were effected in reactions with norbornadiene, 1,5-cyclooctadiene and pinenes. Toluenesulfonyl

Free radical additions. part viii. PMO-t
Free radical additions. part viii. PMO-treatment of dicyanomethyl and trifluoromethyl radical additions to various alkenes
โœ Klaus Riemenschneider; Herbert Bartels; Wolfgang Eichel; Peter Boldt ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 220 KB

Since the elucidation of the anti-Markownikoff addition of hydrogen bromide to alkenes as radical reaction 2,3) there has been a controversial discussion about factors governing regioselectivity and reactivity in free radical additions 4). Although the PMO-treatment of chemical reactivity 5,6)