Free radical additions. Part II: Free radical cyclization of citronellol (Short communication)
β Scribed by E. van Bruggen
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 111 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0165-0513
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π SIMILAR VOLUMES
Bromomalononitrile adds to alkenes in a fast exothermic radical chain reaction (see scheme below) 2,3) . The addition is well examined with respect to prepara-Scheme
Since the elucidation of the anti-Markownikoff addition of hydrogen bromide to alkenes as radical reaction 2,3) there has been a controversial discussion about factors governing regioselectivity and reactivity in free radical additions 4). Although the PMO-treatment of chemical reactivity 5,6)
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