𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Free radical additions. part viii. PMO-treatment of dicyanomethyl and trifluoromethyl radical additions to various alkenes

✍ Scribed by Klaus Riemenschneider; Herbert Bartels; Wolfgang Eichel; Peter Boldt

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
220 KB
Volume
20
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Since the elucidation of the anti-Markownikoff addition of hydrogen bromide to alkenes as radical reaction 2,3) there has been a controversial discussion about factors governing regioselectivity and reactivity in free radical additions 4).

Although the PMO-treatment of chemical reactivity 5,6)

πŸ“œ SIMILAR VOLUMES

Electron Transfer Initiated Free Radical
Electron Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides and Diiodides to Alkenes
✍ Metzger, JΓΌRgen O. ;Mahler, Ralf ;Schmidt, Andreas πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 393 KB

## Abstract Perfluoroalkyl iodides were added in very good yields to 1,2‐dialkyl substituted double bonds of e.g. petroselinic acid initiated by lead/copper(II) acetate in methanol and by copper without solvent, respectively. Using the new initiator system lead/copper(II) acetate, we also obtained

Nucleophilic and Free-Radical Additions
Nucleophilic and Free-Radical Additions of Phosphines and Phosphine Chalcogenides to Alkenes and Alkynes
✍ Svetlana N. Arbuzova; Nina K. Gusarova; Boris A. Trofimov πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 8 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.