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ChemInform Abstract: Imidyl Radicals. Part 2. Radical Addition of N-Chlorophthalimide and N-Bromophthalimide to Alkenes.

✍ Scribed by A. KIRSCH; U. LUENING

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Imidyl radicals. 3. Stereoselectivity of
Imidyl radicals. 3. Stereoselectivity of radical additions of N-haloimides to cyclic alkenes
✍ AndrΓ© Kirsch; Ulrich LΓΌning; Oliver KrΓΌger πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 66 KB πŸ‘ 1 views

N-Haloimides (1 -5) are used in two types of radical chain reactions: (i) the selective Ziegler bromination of allylic and benzylic positions [1], which are bromine atom chain reactions [2] and (ii) imidyl radical [3, 4] chain reactions like substitutions and especially additions to double bonds [5,

Radical Addition of N-Bromophthalimide t
Radical Addition of N-Bromophthalimide to Linear and Cyclic Alkynes
✍ Uta Wille; Oliver KrΓΌger; AndrΓ© Kirsch; Ulrich LΓΌning πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 282 KB πŸ‘ 2 views

Addition of N-bromophthalimide (1) to alkynes 3 via can be explained by the Curtin-Hammett principle. When this free-radical addition is applied to the medium-sized phthalimidyl radicals 2 introduces a bromine atom and an imidyl moiety to vicinal C atoms, and highly functionalized cycloalkyne 8, the