Free radical addition of oxygen containing compounds to internal perfluoroolefins
โ Scribed by M.A. Kurykin; B.L. Tumanskii; N.N. Bubnov; S.P. Solodovnikov; L.S. German af]Institute of Organo-Element Compounds; Academy Of Sciences of the
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 30 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-1139
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๐ SIMILAR VOLUMES
Unsaturated fatty acids such as oleic acid are 1,2-dialkyl substituted alkenes, which can be functionalized by free radical addition to the C,Cdouble bond. We have been able to add enolizable compounds, e. g. acetone, acetic acid and malonic acid to methyl oleate mediated by manga- nese(II1)acetate.
Persistent cyclic acyloxy aminoxyl radicals can be obtained by intramolecular trapping of benzoyl radicals by adjacent aromatic nitro groups whereas analogous intermolecular acyloxy adducts decay by N-O cleavage to give C-nitroso compounds and ultimately acyl aminoxyls. Iwamura and Inamoto' were se