Free radicals derived from some alkyl substituted cyclohexanol derivatives react with hexafluoropropene to give a variety of polyfluoroalkylated adducts. Stereochemistry of the processes is discussed and remote functionalisation of the methyl group in Chemie freier Radikale. 13. Addition von Alkylcy
Free radical addition of F-alkyl compounds to unsaturated carboxylic anhydrides and their derivatives
β Scribed by Neal O. Brace
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 91 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-1139
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and treated with lBuCl (1.18 g, 12.8 mmol) directly after filtration. The mixture was stirred at room temperature for 12 h before the orange solution was evaporated to dryness. Recrystallization of the residue from toluene (ca. 30 mL) affords a yellow crystalline powder (2.50 g, 40%). which decompos
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