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Formation, Structure and Reactivity of Boryloxycarbyne Complexes of Group 6 Metals

โœ Scribed by Holger Braunschweig; Karl W. Klinkhammer; Margot Koster; Krzysztof Radacki

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
157 KB
Volume
9
Category
Article
ISSN
0947-6539

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## Abstract We present the synthesis and characterization of the firsttrisilaโ€bridged __ansa__ halfโ€sandwich complexes of Group 6 transition metals in a oneโ€step synthesis from dilithiatedprecursors Li[M(ฮท^5^โ€C~5~H~4~Li)(CO)~3~] (M = W, Mo) by use ofstoichiometric amounts of Si~3~Me~6~Cl~2~ under d