✦ LIBER ✦

Formation of Sodium Cluster Ions in Electrospray Mass Spectrometry

✍ Scribed by Shaolian Zhou; Matthias Hamburger

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 293 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(199605)10:7<797::aid-rcm550>3.0.co;2-7

No coin nor oath required. For personal study only.

✦ Synopsis

A series of sodium cluster ions, such as Na+(NaCl),, Na'(HCOONa), and Na+(HCOONa),,(CH,C00Na)n2, were observed in electrospray mass spectrometry. These results support the electrophoretic separation mechanism for excess ions at droplet surface, and the charged residue model for gas phase ion formation from highly-charged droplets.

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