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Direct Evidence of Solvent-Peroxovanadium Clusters by Electrospray Ionization Mass Spectrometry

✍ Scribed by Olga Bortolini; Valeria Conte; Fulvio Di Furia; Stefano Moro

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 262 KB
Volume: 1998
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199808)1998:8<1193::aid-ejic1193>3.0.co;2-j

No coin nor oath required. For personal study only.

✦ Synopsis

Electrospray Ionization Mass Spectrometry (ESI-MS)

obtained clearly indicate that the exchange reactions between water and methanol molecules, within the measurements and ab initio calculations on [OV(O 2 )(H 2 O) m -(CH 3 OH) n ] + (m,n: 0-4) peroxo cations have been carried out. coordination sphere of monoperoxo-vanadium complexes, is a conceivable and fast process. This experimental technique allowed the direct observation of the above mentioned species for the first time. The results

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