A change in the mechanism of biomimetic oxidation of tertiary amines in response to appropriate structural features of the substrate, emerges from the investigation of the product pattern from N-benzylaziridine under bona fide radical or electron transfer conditions. This substrate is an amine endow
โฆ LIBER โฆ
Formation of quinones in the iron porphyrin catalyzed oxidation of benzene and alkylbenzenes by magnesium monoperoxyphthalate
โ Scribed by Enrico Baciocchi; Osvaldo Lanzalunga; Andrea Lapi
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 134 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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was detected and shown to be an iodosylbenzene(salen)iron(iii)complex. We hope this new knowledge will be of interest to those scientists who deal with metal-salen catalytic systems and asymmetric oxidation of sulfides, and foresee further ligand designs to improve the enantioselectivity.