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Synthesis of Sulfoxides by the Hydrogen Peroxide Induced Oxidation of Sulfides Catalyzed by Iron Tetrakis(pentafluorophenyl)porphyrin: Scope and Chemoselectivity.

✍ Scribed by Enrico Baciocchi; Maria Francesca Gerini; Andrea Lapi


Publisher
John Wiley and Sons
Year
2004
Weight
195 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The mild oxidation of sulfides to sulfoxides with an aqueous solution of H~2~O~2~ (35%) catalyzed by __in situ__ generated dodecyl hydrogen sulfate as BrΓΈnsted acid surfactant in the absence of any organic co‐solvents and under metal‐free conditions is described. The method shows high c