Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation

✍ Scribed by Konstantin P. Bryliakov; Evgenii P. Talsi

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 159 KB
• Volume: 43
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.200460108

✦ Synopsis

was detected and shown to be an iodosylbenzene(salen)iron(iii)complex. We hope this new knowledge will be of interest to those scientists who deal with metal-salen catalytic systems and asymmetric oxidation of sulfides, and foresee further ligand designs to improve the enantioselectivity.