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Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation

โœ Scribed by Konstantin P. Bryliakov; Evgenii P. Talsi

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
158 KB
Volume
116
Category
Article
ISSN
0044-8249

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Evidence for the Formation of an Iodosyl
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation
โœ Konstantin P. Bryliakov; Evgenii P. Talsi ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 159 KB

was detected and shown to be an iodosylbenzene(salen)iron(iii)complex. We hope this new knowledge will be of interest to those scientists who deal with metal-salen catalytic systems and asymmetric oxidation of sulfides, and foresee further ligand designs to improve the enantioselectivity.