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Formal Total Synthesis of Salicylihalamides A and B

✍ Scribed by Holloway, Georgina A.; Hügel, Helmut M.; Rizzacasa, Mark A.

Book ID: 125546699
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 127 KB
Volume: 68
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo026798h

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We have devised a total synthesis of (12R,13S,15R) salicylihalamides A and B, which allowed revision of the absolute stereochemistry of the natural compounds. The same strategy was then applied to the preparation of naturally occurring salicylihalamides.